Thermoplastic Elastomers (TPE)

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Thermoplastic Elastomers (TPE)

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Thermoplastic elastomers (TPE), sometimes referred to as thermoplastic rubbers (TPR), are a class of copolymers or a physical mix of polymers (usually a plastic and a rubber) that consist of materials with both thermoplastic and elastomeric properties.
While most elastomers are thermosets, thermoplastics are in contrast relatively easy to use in manufacturing, for example, by injection molding. Thermoplastic elastomers show advantages typical of both rubbery materials and plastic materials.
We are committed to providing advanced extruder for all kind of TPE compounding (TPE / TPV / TPU / TPA). We would like to share the experience for the following special application:



Table of Contents


Six Generic Classes of Commercial TPEs

Applications

Experience for Special Applications

1. Thermoplastic Vulcanizates, TPV
If EDPM is in Pellet Form
If EDPM is in Block Form
2. TPR Compounding for Shoes                                                                                                                     


Six Generic Classes of Commercial TPEs

Styrenic block copolymers, TPS (TPE-s)                                                                               
Thermoplastic polyolefinelastomers, TPO (TPE-o)
Thermoplastic Vulcanizates, TPV (TPE-v or TPV)
Thermoplastic polyurethanes, TPU (TPU)
Thermoplastic copolyester, TPC (TPE-E)
Thermoplastic polyamides, TPA (TPE-A)


Applications

Automotive (Dust cover, Triangular window, Air filter, Hand break, etc.)
Wire and cable (Electric cable, Ignition wire, Headphone wire, Connector plugs, etc.)
Construction & Transportation (Sealing strip, Expansion joint, Metro pads, etc.)
Other Industrial (Drain pipe, Handle, Cup mat, foot pad, Shoes, etc.)


Experience for Special Applications

1. Thermoplastic Vulcanizates, TPV
TPV is a thermoplastic dynamic full vulcanizate, which is made by dynamically vulcanizing the rubber in a molten plastic phase. In this process, rubber is sheared into micron-sized vulcanizate particles, forming a rubber-plastic two-phase system with sea-island structure. The two-phase system makes the TPV material obtain characteristics of both rubber and plastics, such as thermoplastic process-ability, complete recyclability, and high resilience. The product can replace rubber, save energy, and is environment friendly.
TPV compounding needs a two-step process and different machines, according to the raw material.
If EDPM is in Pellet Form


1) The first step: applying twin screw extruded for premixing, blending, and absorbing oil


Need special screw elements for premixing the liquid and polymer.

Water ring pelletizing is enough for this process.

One big extruder can supply the material for several small extruder on the second step.

Basic formula:

PP (20~30%), EDPM in Pellets Form (40~50%), CaCO3 (10~20%), Oil (0-15%), Additives(2~10%).


Technical Specifications of Extruder:

Type Screw diameter (mm) Max. torque per shaft (Nm) Output(kg/h)
GS75 71.4 500 500-600
GS95 93 500 800-900



2) The second step: using the twin screw extruder for reacting compounding


Need long L/D and high torque gearbox for enough reacting time and dispersion

Small extruder with less clearance is key points for this process.

Need special screw elements for premixing the liquid and polymer.

Premixing and volumetric feeding is enough for this step process.

According to the Hardness of final pellets, we can choose water ring pelletizing or Under water pelletizing.


Basic formula:

Pellets for the first step process, Vulcanizing Agent, the Extra Oil, Other Additives.


Technical Specifications of Extruder:

Type Screw diameter (mm) Max. torque per shaft (Nm) Output(kg/h)
GS52 51.4 600 200-300
GS65 62.4 600 300-400
GS75 71.4 600 500-600


If EDPM is in Block Form

1) The first step: kneader for premixing with CaCO3 and absorbing all of the oil

Subsequently, apply force feeding into one single screw extruder for pelletizing or crushing into small pieces.


Basic formula:

EDPM in block form, CaCO3 (10~20%), Oil (0-30%), Additives(2~10%).


Technical Specifications of Kneader & Single Screw Extruder:

Type Screw diameter (mm) Kneader Output(kg/h)
GS-100 100 35 200-300
GS-120 120 55-75 400-600
GS-150 150 110 800-1000
GS-180 180 150 1000-1500


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2) The second step: using twin screw extruder for reacting compounding


Need long L/D and high torque gearbox for enough reacting time and dispersion.

Need special screw elements for premixing the liquid and polymer.

Loss-in-weight feeding is better for this step process.

According to the Hardness of final pellets, we can choose water ring pelletizing or under water pelletizing.


Basic formula:

PP, Pellet for the first step process, Vulcanizing Agent, Other Additives.


Technical Specifications of Extruder:

Type Kneader Screw Dia(mm) Output(kg/h)
GS50-100 55 50.5/100mm 200-300
GS65-150 75 62.4/150mm 400-500
GS75-180 110 71/180mm 600-800
GS95-200 150 93/200mm 1000-1500

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2. TPR Compounding for Shoes


Comparing to the traditional process (kneader + single extruder), the twin screw extruder can generate more output and better dispersion.

The color can be easily manipulated and changed.

Water ring pelletizing.


Basic formula:

HIPS/CPPS + SBS + Paraffin Oil + CaCO3 + Silica + EVA + Stabilizer + Additives

Technical Specifications of Extruder:

Type Screw diameter (mm) Max. Speed (rpm) Output(kg/h)
GS65 62.4 500 400-500
GS75 71.4 500 700-800

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